Stereoselectivity of the Interactions of Thioglucoside Glucohydro- Lase and Epithiospecifier Protein from Various Sources*

نویسنده

  • RICHARD J. PETROSKI
چکیده

(S)-2-Hydroxy-3-butenylglucosinolate (epi-progoitrin) was converted to erythroand threo-1-eyano-2-hydroxy3,4-epithiobutanes by combinations of th~oglucoside glucohydrolase and epithiospecifier protein (ESP) from various sources. In all combinations studied the erythro/threo product ratio was about 1.4, except when the thioglucoside glucohydrolase was from Sinapis alba L. and the ESP from Brassica campestris in which case the ratio was about 1.8.

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تاریخ انتشار 2007